Liman: 'Pitt and Jolie chemistry was immediate'

Alleged couple Brad Pitt and Angelina Jolie had immediate chemistry from the first day of the filming on Mr and Mrs Smith, according to the movie's director Doug Liman.

The Bourne Identity film-maker cast Jolie at the last minute to replace Pitt's original co-star Nicole Kidman, who was called back to film additional scenes for The Stepford Wives, and so the pair only met for the first time on the set.